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81.
Triple Positive Solutions of Boundary Value Problems for High-order Fractional Differential Equation at Resonance with Singularities 下载免费PDF全文
In this paper, we investigate the existence of triple positive solutions of boundary value problems for high-order fractional differential equation at resonance with singularities by using the fixed point index theory and the Leggett-Williams theorem. The spectral theory and some new height functions are also employed to establish the existence of triple positive solutions. The nonlinearity involved is arbitrary fractional derivative, and permits singularity. 相似文献
82.
Alexander Koldobsky 《Journal of Theoretical Probability》1994,7(1):135-145
Let μ be a measure in a Banach spaceE, f be an even function onR. We consider the potentialg(a)=f E f(‖x?a‖)dμ(x). The question is as follows: For whichf does the potentialg determine μ uniquely? In this article we give answers in the cases whereE=l ∞ n and wheref(t)=|t| p andE is a finite dimensional Banach space with symmetric analytic norm. Calculating the Fourier transform of the functionf(‖x‖ ∞) we give a new proof of the J. Misiewicz's result that the functionf(‖x‖ ∞) is positive definite only iff is a constant function. 相似文献
83.
Sergiu Aizicovici Viorel Barbu 《NoDEA : Nonlinear Differential Equations and Applications》1996,3(1):1-18
A non-Fourier phase field model is considered. A global existence result for a Dirichlet, or generalized Neumann, initial-boundary value problem is obtained, followed by a discussion of the regularity and asymptotic properties of solutions ast.This research was supported in part by the National Science Foundation under Grant DMS 91-11794 and in part by the Italian M.U.R.S.T. project Problemi non lineari...Part of this author's work was done while visiting Ohio University. 相似文献
84.
Best possibility of the Furuta inequality 总被引:5,自引:0,他引:5
Let , and . Furuta (1987) proved that if bounded linear operators on a Hilbert space satisfy , then . In this paper, we prove that the range and is best possible with respect to the Furuta inequality, that is, if or , then there exist which satisfy but .
85.
The effect of geometry modifications of13C chemical shifts has been investigated in a small subset of molecules using both LO-INDO and Gaussian 70 (4–31) calculations. The Gaussian calculations, while known to give poor absolute shifts, compare well to the reparameterized semi-empirical INDO determinations in calculated shift changes. In virtually all cases the signs of the shift changes were found to be opposite to that of the changes in the calculated electronic energy. 相似文献
86.
Massimo Ragazzi Paola Carbone Dino R. Ferro 《International journal of quantum chemistry》2002,88(5):663-669
Cycloolefin copolymers (COC) have recently raised much interest because of their excellent thermal and optical properties, largely determined by the chain composition and stereochemistry. Previous force‐field computations allowed us to define the main conformational characteristics of ethylene–norbornene (E–N) copolymers and to contribute to the elucidation of their microstructure on the basis of empirical relationships between conformation and 13C nuclear magnetic resonance (NMR) chemical shifts. A thorough test of ab initio 13C chemical shifts computations [gauge‐invariant atomic orbitals (GIAO)] on known cases shows that the agreement with experimental data is quite good, especially with the MPW1PW91 density functional theory (DFT), using the 6‐311+G(2d,p) basis set on properly energy‐minimized structures. We applied this method on proper model compounds to confirm the signal assignment of the spectra of E–N copolymers in the presence of norbornene microblocks, where strong effects arising from ring distortions are expected to occur. The results nicely confirm the latest assignment of norbornene signals belonging to ENNE sequences. This shows the great potentialities of GIAO/DFT computations with regard to complex spectra interpretation and polymer microstructural investigations. © 2002 Wiley Periodicals, Inc. Int J Quantum Chem, 2002 相似文献
87.
Isolated polyfluorobenzene (PFB) molecules and their protonated forms are investigated by the AM1 method with full geometry optimization. The proton affinities of PFB are estimated for different protonated positions. The proton affinity of PFB averaged over all isomers is shown to decrease monotonically as the number of fluorine atoms in the molecule increases. The relative populations of different isomers of arenonium ions (AI) formed by PFB protonation are determined. From the calculated data, the value of + for the F atom in theipso-position is estimated as 1.00. The activation energies of the 1,2-hydrogen shifts in AI are calculated. The dependences of the proton affinity and the activation energies of 1,2-hydrogen shifts on the number of halogen atoms are found to have distinct characters for PFB and polychlorobenzenes. The physical reasons for these difference are discussed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1878–1882, November, 1993. 相似文献
88.
Yu. B. Vysotsky V. S. Bryantsev O. A. Gorban 《Chemistry of Heterocyclic Compounds》2002,38(12):1451-1468
The effects of benzannellation, phenyl substitution at the nitrogen atom, protonation at the carbene carbon, ionization, and the state of the carbene center (2 or 2) on the electronic structure, diamagnetic susceptibility, induced -electron ring currents, the 1H, 13C, and 14N chemical shifts, and the energies of the lowest electronic transitions of imidazol-2-ylidenes and their oxo and thio analogs were examined in the bound version of -electron perturbation theory. The calculated and experimental data are compared. 相似文献
89.
B. I. Ugrak Yu. A. Manaev V. P. Perevalov S. A. Shevelev 《Russian Chemical Bulletin》1992,41(11):2012-2017
The15N NMR chemical shifts and15N-1H SSCCs are presented for substituted N-methylpyrazoles with substituents such as CH3, NO2, Br, Cl, NH2, O=CNH2, O=CPh, and COOH at the carbon atoms. The15N chemical shifts of the cyclic atoms of nitrogen and the nitro groups are discussed as well as the geminal and vicinal SSCCs of the ring nitrogen atoms with the hydrogen atoms of the CH and CH3 fragments.N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 117334 Moscow. D. I. Mendeleev Chemico-Technological Institute, Moscow, Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 11, pp. 2554–2561, November, 1992. 相似文献
90.
Nuclear magnetic resonance spectroscopic study on ionic liquids of 1-alkyl-3-methylimidazolium salts
Chemical shifts of 1H and 13C NMR of series of methylimidazolium salts (MIM+, X=Br−, BF4− and PF6−) function on the length of alkyl groups on the ring, type of solvents and the concentration. The bromides series demonstrate more chemical shift variation on H2 upon the change of solvents and concentration. Unexpected H-D exchange reactions were also observed in the MIM+Br− by using CD3OD and D2O. The exchange rates strongly depend on the length of the alkyl group, which could cause more steric factor to reduce the interaction between deuterium atom from solvent and C2 of the ring. 相似文献